First three-dimensional actinide polyrotaxane framework mediated by windmill-like six-connected oligomeric uranyl: dual roles of the pseudorotaxane precursor.

نویسندگان

  • Lei Mei
  • Zhen-Ni Xie
  • Kong-Qiu Hu
  • Lin Wang
  • Li-Yong Yuan
  • Zi-Jie Li
  • Zhi-Fang Chai
  • Wei-Qun Shi
چکیده

The first 3D actinide polyrotaxane framework (named IHEP-URCP-2) has been obtained based on windmill-like six-connected high-nuclear oligomeric uranyl nodes under hydrothermal conditions. Notably, the in situ formed pseudorotaxane ligand simultaneously plays dual roles of both a bulky pseudorotaxane linker and a supramolecular guest.

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عنوان ژورنال:
  • Dalton transactions

دوره 45 34  شماره 

صفحات  -

تاریخ انتشار 2016